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You are seeing more than 1 CPU because of hyperthreading were the CPU runs as 2 virtual cores supporting a thread each.
Your RAM is a bit slow, you can get great 800mhz RAM relatively cheaply and to be honest until DDR3 prices drop and their timmings get alot tighter it isn't worth the cash for the slight improvement you'll see.
PSU you can get 750watt ones that should run any new comp with a single high end video card.
Any on of the mid to high graphics cards should run Aion fine so you don't have to break your bank to do it.
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